Novel lithography-free method yields durable antireflective glass surfaces
A team of researchers from ICFO and Corning Incorporated has developed a new method for fabricating anti-reflective (AR) surfaces achieved through nano-structured surfaces using a lithography-free process. The innovative method, described in the journal ACS Applied Materials and Interfaces, utilizes thermally dewetted silver as an etching mask to create nanohole structures on glass surfaces, significantly reducing light reflection.
Anti-reflective (AR) surfaces minimize unwanted reflections, enhancing the efficiency of various optical devices such as laser optics, camera lenses, eyeglasses, touchscreen displays, and solar harvesting systems. Researchers and engineers have developed several alternative strategies to the traditional multilayer anti-reflective coating procedure to increase the performance and versatility of optical devices. Using bio-inspired nano-scale structures, such as nanopillars or nanoholes, directly onto a substrate surface enables the manipulation of light paths and reduces the reflection across a broad spectrum and wide range of angles.
However, the fabrication of these nano-structured surfaces with the desired properties is rather complex, often involving multistep lithography methods, limiting their widespread adoption due to cost and scalability constraints.
Now, in a new study, ICFO researchers Iliyan Karadzhov, Bruno Paulillo, and Juan Rombaut, led by ICREA Professor at ICFO Valerio Pruneri, in collaboration with Corning Incorporated researchers Karl W. Koch and Prantik Mazumder, describe a simplified method that achieves nanostructured AR surfaces. This approach uses thermally dewetted thin silver films as etching masks to generate subwavelength nanohole structures on the glass surfaces, characterized by its simplicity and cost-effectiveness by avoiding complex lithography.Researchers recently published the results of this study in the journal ACS Applied Materials and Interfaces.
Silver and nickel layers
The fabrication process consists of three main steps. First, the rapid thermal annealing of an ultra-thin silver film onto a glass substrate produces silver nanoparticles. Second, the deposition of a thin nickel layer over these nanoparticles and selective chemical wet etching create a secondary etching mask. Finally, a dry etching process uses this mask to carve nanoholes of varying depths into the glass surface.
Schematic illustration of the three main steps of the new method
“Nanoholes are tiny, irregularly arranged cavities on a surface that significantly reduce light reflection by smoothly transitioning the refractive index from air to substrate,” explains Iliyan Karadzhov, an early-stage researcher at ICFO in the NANO-GLASS project. “They were chosen for their superior mechanical durability compared to other nanostructures like nanopillars and their ability to provide excellent AR properties with minimal light scattering,” adds the first author of the study.
The initial thickness of the silver film and the duration of the dry etch process determine the final arrangement and depth of these nanoholes. The team fabricated several samples with varying initial masks and hole depths, testing their performance by measuring both transmittance and reflectance in the visible and near-infrared ranges. The newly developed AR surfaces exhibited a broadband omnidirectional response that achieves transmittance levels exceeding 99% in both the visible and near-infrared ranges, as well as maintaining high transmittance even at steep angles of incidence (up to 60 degrees).
Lateral view of the nanoholes carved on the glass substrate taken with Scanning electron microscope (SEM) showing their depth.
Durable surfaces
The samples also demonstrated mechanical robustness and durability in abrasion tests. “One challenge was ensuring that the nanohole structures remained intact during abrasion tests while maintaining high optical performance,” recalls Karl W. Koch, a researcher at Corning Incorporated. “This was overcome by optimizing the nanoholes’ geometry and the fabrication process to balance the mechanical and optical properties. Another challenge was scaling the fabrication method for large-area applications, which was addressed by leveraging scalable techniques like thermal dewetting,” he adds.
“This process not only simplifies the fabrication of nanostructured antireflective surfaces but also enhances the mechanical resistance to abrasion, a critical factor for various applications,” has stated Prantik Mazumder, a Corning Incorporated researcher.
“This new lithography-free method provides new possible solutions to the development of optoelectronic devices that require high transmission and durability,” concluded Valerio Pruneri, the leading author of the study and NANO-GLASS project coordinator.
Original article
Karadzhov, I., Paulillo, B., Rombaut, J., Koch, K.W., Mazumder, P., and Pruneri, V. Mechanically-durable antireflective subwavelength nanoholes on glass surfaces using lithography-free fabrication. ACS Appl. Mater. Interfaces 2024, 16, 15, 19672–19680. DOI: http://doi.org/10.1021/acsami.3c15391
This project has received funding from the European Union’s Horizon 2020 research and innovation programme under Marie Sklodowska-Curie grant agreement nº 956419
